PC/PBT 6620U玻璃纖維增強(qiáng)PBT
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PBT耐熱水解性的影響因素是端羧基濃度。由于PBT含有酯鍵,在高于其玻璃化轉(zhuǎn)變溫度的溫度下置于水中會(huì)發(fā)生酯鍵斷裂,水解形成的酸性環(huán)境使水解加速反應(yīng),性能急劇下降。
PBT耐熱水解性的解決方法:
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一是是通過(guò)添加封閉PBT端羧基的方法,降低端羧基濃度,提高PBT的抗水解性,如加入帶環(huán)氧官能團(tuán)的助劑(如SAG系列,一種乙烯-丙烯腈-GMA的無(wú)規(guī)共聚物),通過(guò)官能團(tuán)GMA與PBT端羧基反應(yīng)來(lái)封端,從而提高PBT的抗水解性。
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二是添加水解穩(wěn)定劑,如碳化二亞胺,水解穩(wěn)定劑會(huì)消耗水解產(chǎn)生的羧基,減緩PBT的酸性水解速度,提高PBT樹(shù)脂的抗水解性。
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以下是美國(guó)杜邦Crastin PBT熱塑性聚酯樹(shù)脂 部分型號(hào)說(shuō)明表!
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Blow Moldable Resins打擊可塑樹(shù)脂
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Crastin? BM6450XD BK560CBlow molding grade (compatable with Hytrel? co-extrusion and blow molding)吹塑級(jí)(與Hytrel對(duì)照表?共擠和吹塑)
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Extrusion Resins擠壓樹(shù)脂
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Crastin? 6130C NC010Unreinforced, medium high viscosity polybutylene terephthalate resin for extrusion and injection molding.無(wú)筋,介質(zhì)高粘度樹(shù)脂為擠出和注塑成型。
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Crastin? 6131C NC010Unreinforced, low viscosity PBT resin for extrusion and injection molding無(wú)筋、低粘度 樹(shù)脂為擠出和注塑成型。
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Crastin? FG6129 NC010 An unreinforced, medium viscosity polybutylene terephthalate resin for extrusion and injection molding. 非強(qiáng)化,介質(zhì)粘度樹(shù)脂為擠出和注塑成型。
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Crastin? FG6130 NC010 Unreinforced, medium high viscosity PBT resin for extrusion and injection molding. 無(wú)筋,介質(zhì)高粘度 樹(shù)脂為擠出和注塑成型。
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Crastin? ST820 BK503Unreinforced, Super Tough, black polybutylene terephthalate resin for injection molding.無(wú)筋,強(qiáng)硬,黑色? 樹(shù)脂為注射成型。
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Crastin? ST820 NC010Unreinforced, Super Tough polybutylene terephthalate resin for injection molding.無(wú)筋,難的? 樹(shù)脂為注射成型。
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Flame Retardant Resins阻燃樹(shù)脂
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Crastin? HTI668FR NC01045% Glass and mineral reinforced, 45%的玻璃和礦物鋼筋,
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Crastin? LW9020FR BK85120% Glass fibre reinforced, flame retardant, PBT blend for injection molding.20%的玻璃纖維增強(qiáng)、阻燃、PBT混合為注射成型。
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Crastin? LW9020FR NC01020% Glass fibre reinforced, flame retardant, PBT blend for injection molding.20%的玻璃纖維增強(qiáng)、阻燃、PBT混合為注射成型。
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Crastin? LW9030FR BK85130% Glass fiber reinforced polybutylene terephthalate alloy30%的玻璃纖維增強(qiáng)? 合金
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Crastin? LW9030FR NC01030% Glass fiber reinforced polybutylene terephthalate alloy30%的玻璃纖維增強(qiáng)? 合金
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Crastin? S650FR BK851 An unreinforced, black, flame retardant polybutylene terephthalate for injection molding.非強(qiáng)化、黑色、阻燃? 對(duì)注射成型。
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Crastin? S650FR NC010 An unreinforced, flame retardant polybutylene terephthalate for injection molding.非強(qiáng)化、阻燃? 對(duì)注射成型。
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Crastin? SK642FR NC010? 15% Glass fibre reinforced, flame retardant polybutylene terephthalate for injection moulding.15%的玻璃纖維增強(qiáng)、阻燃? 為注射模塑。
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Crastin? SK645FR BK851? A flame retardant, 30% glass reinforced black polybutylene terephthalate molding resin. 阻燃劑,30%玻璃增強(qiáng)黑? 成型樹(shù)脂。
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Crastin? T835FRUV NC0105% Glass reinforced, toughened, flame retardant PBT5%的玻璃纖維,鋼化、阻燃
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Low Warp Resins低經(jīng)樹(shù)脂
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Crastin? LW9320 BK851 20% Glass fiber reinforced, black polybutylene terephthalate alloy for injection molding. 20%的玻璃纖維增強(qiáng)、黑? 合金注射成型。
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Crastin? LW9320 NC010 20% Glass fiber reinforced polybutylene terephthalate alloy for injection molding. 20%的玻璃纖維增強(qiáng)? 合金注射成型。
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Crastin? LW9330 BK851 30% Glass fiber reinforced, black polybutylene terephthalate alloy for injection molding. 30%的玻璃纖維增強(qiáng)、黑? 合金注射成型。
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Crastin? LW9330 NC010 30% Glass fiber reinforced polybutylene terephthalate alloy for injection molding. 30%的玻璃纖維增強(qiáng)? 合金注射成型。